By 鈴木, 基之, 1941- 鈴木, 基之, ; Motoyuki Suzuki
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Extra info for Adsorption engineering
At higher coverage, measured isosteric heat of adsorption seems to decrease with increasing amount adsorbed. 3. Agreement between them is reasonable. At low coverage, the Freundllch isotherm assumes existence of sites with very high heat of adsorption. For measured equilibrium data, the Radke and Prausnitz equation can be used for correlating low coverage data. Temperature dependence of K gives heat of adsorpt~onat initial coverage. 6 J / m o l and is shown in Fig. 18 by the arrow. 18, transition from Henry type isotherm and Freundlich type isotherm can be said to occur at around 4X 10-lmol/kg.
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Temperature, T, is called the adsorption isotherm at T. The relation between concentration and temperature yielding a given amount adsorbed, q, is called the adsorption isostere (Fig. 3 2). C = C ( T ) for q (3-2) Adsorprion lsorherms 37 Adsorption isotherms are described in many mathematical forms, some of which are based on a simplified physical picture of adsorption and desorption, while others are purely empirical and intended to correlate the experimental data in simple equations with two o r at most threeempirical parameters: the more the number of empirical parameters, the better the fit between experimental data and the empirical equation.
Adsorption engineering by 鈴木, 基之, 1941- 鈴木, 基之, ; Motoyuki Suzuki