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By Hanspeter Pfander, Synnøve Liaaen-Jensen, George Britton (auth.), Dr. George Britton, Professor Dr. Dr. h. c. Synnøve Liaaen-Jensen, Professor Dr. Dr. h. c. Hanspeter Pfander (eds.)

ISBN-10: 303489323X

ISBN-13: 9783034893237

ISBN-10: 3034893256

ISBN-13: 9783034893251

George Britton, Synnl/Jve Liaaen-Jensen and Hanspeter Pfander This publication, quantity 2 within the sequence Carotenoids, is the 1st booklet to be released that's dedicated completely to the complete synthesis of carotenoids, however it is well timed in view of the fast improvement and the starting to be diversification of the carotenoid box. The 1971 Carotenoids publication contained an incredible bankruptcy of 250 pages on overall synthesis by means of H. Mayer and O. Isler. That entire and authoritative evaluation defined systematically the development of many synthons and the synthesis of many usual and unnatural carotenoids and similar compounds. Twenty 5 years on, that bankruptcy is still an important reference paintings and resource of data, with its large number of tabulated information and lists of references to the unique literature. Surveys of growth on account that 1971 were provided on the IUPAC overseas Symposia on Carotenoids and are integrated within the released complaints of those symposia. The historical past of significant courses within the carotenoid box, resulting in the improvement of this sequence, was once defined within the preface to the sequence released in Vol. IA. the final philo­ sophy defined in that preface, with emphasis on useful information and the inclusion of labored examples of a few of the main necessary approaches, is maintained in Vol. 2. In kceping with this philosophy, Vol. 2 isn't really meant to be an exhaustive evaluation of the literature, yet is deliberate as a realistic booklet, in addition to a resource of information.

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Widmer, M. Soukup, R. Zell, E. Brager, H. P. Wagner and M. Imfeld, Helv. Chirn. Acta, 73, 861 (1990). M. Soukup, E. Widmer and T. Lukac, Helv. Chirn. Acta, 73, 868 (1990). K. Bernhard and H. Mayer, Pure App/. , 63, 35 (1991). H. Pfander, Pure App/. , 67,728 (1985). J. P. Wolf and H. Pfander, Helv. Chirn. Acta, 69,62 (1986). A. Ishida and T. Huhaiyama, Chern. , 1127 (1976). J. E. McMurry and M. P. Fleming, 1. Arn. Chern. , 96, 4708 (1974). G. BUchi and R. M. Frcidinger, 1. Ar. Chern. , 96, 3332 (1974).

Mayer, Pure Appl. , 51, 535 (1979). A. Riittimann and H. v. Chim. Acta, 63, 1456 (1980). E. Widmer, M. Soukup, R. Zell, E. Brager, H. P. Wagner and M. Imfeld, Helv. Chim. Acta, 73, 861 (1990). M. Soukup, E. Widmer and T. Lukac, He/v. Chim. Acta, 73, 868 (1990). G. Englert, K. Noack, E. Brager, E. Glinz, M. Vecchi and R. ZeIJ, Helv. Chim. Acta, 74, 969 (1991). O. Isler, H. Lindlar, M. Montavon, R. Riiegg, G. Saucy and P. Zeller, Helv. Chim. Acta, 39, 2041 (1956). M. Baranyai, 1. SzaboJcs and G. T6th, Tetrahedron, 32, 867 (1976).

P. UVlVis roC] Ama< [nm] alI-E C"+C IO +C,, Wittig 207 208 7Z C,s + (7Z)-C2S Wittig Isomerization Chromatography (E) 9Z =neo B Isomerization Chromatography 107 348 (8 800), 458 (111700), 488 (94700) (c) 'H-NMR, 'lC-NMR, CD 37, 39 13Z =neo A Isomerization Chromatography 98 347 (39 000), 458 (86 300), 487 (70 200) (c) 'H-NMR. "C-NMR, CD 37, 39 15Z 15,15' -Didehydrozeaxanthin + H21 Lind1ar catalyst Chromatography 336 (45 284), 449 (77 143), 478 (60531) (a) 'H-NMR,CD 37, 38 7Z,7'Z (7Z)-C" + C,o + (7Z)-C" Wittig Isomerization Chromatography 190192 430 (85 847), 455 (121 858).

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Carotenoids: Volume 2: Synthesis by Hanspeter Pfander, Synnøve Liaaen-Jensen, George Britton (auth.), Dr. George Britton, Professor Dr. Dr. h. c. Synnøve Liaaen-Jensen, Professor Dr. Dr. h. c. Hanspeter Pfander (eds.)


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